碳量子点作为一种新型的碳纳米材料,具有优良的生物相容性、低毒性和极强的量子限域效应。综述了林业生物质碳量子点的研究进展,介绍了林业生物质碳量子点的合成方法及表征技术手段,对林业生物质碳量子点的研究方向进行了展望。
As a new type of carbon nanomaterial,carbon quantum dots have excellent biocompatibility,low toxicity and strong quantum limiting effect.The research progress of forestry biomass carbon quantum dots was reviewed.Not only the synthesis and characterization methods of forestry biomass carbon quantum dots were introduced.,but the research direction of forestry biomass carbon quantum dots was prospected.
[1] Rossetti R,Nakahara S,Brus L E.Quantum size effects in the redox potentials,resonance Raman spectra,and electronic spectra of CdS crystallites in aqueous solution[J].The Journal of Chemical Physics,1983,79(2):1086-1088.
[2] 谭翠燕,梁汝强.量子点在生命科学中的应用[J].生物化学与生物物理学报,2002,34(1):1-5.
[3] Talapin D V,Rogach A L,Kornowski A,et al.Highly luminescent monodisperse CdSe and CdSe/ZnS nanocrystals synthesized in a hexadecylamine-trioctylphosphine oxide-trioctylphospine mixture[J].Nano Letters,2001,1(4):207-211.
[4] Du F,Zhang L,Zhang L,et al.Engineered gadolinium-doped carbon dots for magnetic resonance imaging-guided radiotherapy of tumors[J].Biomaterials,2017,121:109-120.
[5] Reshma V G,Mohanan P V.Quantum dots:applications and safety consequences[J].Journal of Luminescence,2019,205:287-298.
[6] Wang Y,Hu A.Carbon quantum dots:synthesis,properties and applications[J].Journal of Materials Chemistry C,2014,2(34):6921-6939.
[7] Xu X,Ray R,Gu Y,et al.Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments[J].Journal of the American Chemical Society,2004,126(40):12736-12737.
[8] Sun Y P,Zhou B,Lin Y,et al.Quantum-sized carbon dots for bright and colorful photoluminescence[J].Journal of the American Chemical Society,2006,128(24):7756-7757.
[9] Wang X,Qu K,Xu B,et al.Multicolor luminescent carbon nanoparticles:synthesis,supramolecular assembly with porphyrin,intrinsic peroxidase-like catalytic activity and applications[J].Nano Research,2011,4(9):908-920.
[10] Dong Y,Zhou N,Lin X,et al.Extraction of electrochemiluminescent oxidized carbon quantum dots from activated carbon[J].Chemistry of Materials,2010,22(21):5895-5899.
[11] Pan L,Sun S,Zhang A,et al.Truly fluorescent excitation-dependent carbon dots and their applications in multicolor cellular imaging and multidimensional sensing[J].Advanced materials,2015,27(47):7782-7787.
[12] Li X,Rui M,Song J,et al.Carbon and graphene quantum dots for optoelectronic and energy devices:a review[J].Advanced Functional Materials,2015,25(31):4929-4947.
[13] Liu C,Zhang P,Zhai X,et al.Nano-carrier for gene delivery and bioimaging based on carbon dots with PEI-passivation enhanced fluorescence[J].Biomaterials,2012,33(13):3604-3613.
[14] Hui L,Huang J,Chen G,et al.Antibacterial property of graphene quantum dots (both source material and bacterial shape matter)[J].ACS Applied Materials & Interfaces,2016,8(1):20-25.
[15] Xu J,Zeng F,Wu H,et al.Preparation of a mitochondria-targeted and NO-releasing nanoplatform and its enhanced pro-apoptotic effect on cancer cell[J].Small,2014,10(18):3750-3760.
[16] Cakici M,Kakarla R R,Alonso-Marroquin F.Advanced electrochemical energy storage supercapacitors based on the flexible carbon fiber fabric-coated with uniform coral-like MnO2 structured electrodes[J].Chemical Engineering Journal,2017,309:151-158.
[17] Son D R,Raghu A V,Reddy K R,et al.Compatibility of thermally reduced graphene with polyesters[J].Journal of Macromolecular Science,Part B,2016,55(11):1099-1110.
[18] Li Y,Gecevicius M,Qiu J.Long persistent phosphors—from fundamentals to applications[J].Chemical Society Reviews,2016,45(8):2090-2136.
[19] Kong B,Zhu A,Ding C,et al.Carbon dot-based inorganic-organic nanosystem for two-photon imaging and biosensing of pH variation in living cells and tissues[J].Advanced Materials,2012,24(43):5844-5848.
[20] Wu Z L,Zhang P,Gao M X,et al.One-pot hydrothermal synthesis of highly luminescent nitrogen-doped amphoteric carbon dots for bioimaging from bombyx mori silk-natural proteins[J].Journal of Materials Chemistry B,2013,1(22):2868-2873.
[21] Sun D,Ban R,Zhang P H,et al.Hair fiber as a precursor for synthesizing of sulfur-and nitrogen-co-doped carbon dots with tunable luminescence properties[J].Carbon,2013,64:424-434.
[22] Wang Q,Huang X,Long Y,et al.Hollow luminescent carbon dots for drug delivery[J].Carbon,2013,59:192-199.
[23] Mehta V N,Jha S,Kailasa S K.One-pot green synthesis of carbon dots by using saccharum officinarum juice for fluorescent imaging of bacteria (Escherichia coli) and yeast (Saccharomyces cerevisiae) cells[J].Materials Science and Engineering:C,2014,38:20-27.
[24] 陈巧玲,陈碧桑,李飞明,等.可乐碳量子点的提取及其抑菌性研究[J].现代食品科技,2018,34(1):52-56.
[25] Zhu L,Yin Y,Wang C F,et al.Plant leaf-derived fluorescent carbon dots for sensing,patterning and coding[J].Journal of Materials Chemistry C,2013,1(32):4925-4932.
[26] GB/T 31741—2015林业生物质能源名词术语:[S].北京:中国标准出版社,2015.
[27] Jelinek,Raz.Carbon quantum dots:synthesis,properties and applications[M].Switzerland:Springer,2017:6.
[28] 郭璇,莫文轩,刘旭亮,等.落叶松木粉水热炭化制备碳量子点及其性能研究[J].林产化学与工业,2017,37(1):109-115.
[29] Yuan H,Zhang X,Li D,et al.Strongly fluorescent carbon quantum dots from biomass tar as highly selective and sensitive probe for Fe3+ detection[J].Nano,2018,13(4):1850043.
[30] Liang Q,Wang Y,Lin F,et al.A facile microwave-hydrothermal synthesis of fluorescent carbon quantum dots from bamboo tar and their application[J].Analytical Methods,2017,9(24):3675-3681.
[31] Wang T,Liu X,Ma C,et al.Bamboo prepared carbon quantum dots (CQDs) for enhancing Bi3Ti4O12 nanosheets photocatalytic activity[J].Journal of Alloys and Compounds,2018,752:106-114.
[32] Liu Y,Zhao Y,Zhang Y.One-step green synthesized fluorescent carbon nanodots from bamboo leaves for copper(Ⅱ) ion detection[J].Sensors and Actuators B:Chemical,2014,196:647-652.
[33] 孙英祥,孙相宝,何志伟,等.桃花水热法一步合成水溶性荧光碳点[J].材料科学与工程学报,2014,32(3):393-397.
[34] Jiang X,Shi Y,Liu X,et al.Synthesis of nitrogen-doped lignin/DES carbon quantum dots as a fluorescent probe for the detection of Fe3+ ions[J].Polymers,2018,10(11):1282.
[35] Xue B,Yang Y,Sun Y,et al.Photoluminescent lignin hybridized carbon quantum dots composites for bioimaging applications[J].International Journal of Biological Macromolecules,2019,122:954-961.
[36] 刘辰,冯文祥,胡倬铭,等.酶解木质素水热法制备碳量子点[J].广东化工,2017,44(12):15-16.
[37] Si M,Zhang J,He Y,et al.Synchronous and rapid preparation of lignin nanoparticles and carbon quantum dots from natural lignocellulose[J].Green Chemistry,2018,20(15):3414-3419.
[38] Yao X,Ma C,Huang H,et al.Solvothermal-assisted synthesis of biomass carbon quantum dots/bismuth oxyiodide microflower for enhanced photocatalytic activity[J].Nano,2018,13(3):1850031.
[39] 梁梓承.生物质碳量子点的制备与应用研究[D].广州:华南理工大学,2016:26.
[40] Wang R,Xia G,Zhong W,et al.Direct transformation of lignin into fluorescence-switchable graphene quantum dots and their application in ultrasensitive profiling of a physiological oxidant[J].Green Chemistry,2019,21(12):3343-3352.
[41] Zhang B,Liu C,Liu Y.A novel one-step approach to synthesize fluorescent carbon nanoparticles[J].European Journal of Inorganic Chemistry,2010,2010(28):4411-4414.
[42] 傅政.碳量子点功能化修饰及其在生物成像与传感中的应用[D].新乡:河南师范大学,2017:17-18.
[43] Zhu S,Meng Q,Wang L,et al.Highly photoluminescent carbon dots for multicolor patterning,sensors,and bioimaging[J].Angewandte Chemie,2013,125(14):4045-4049.
[44] Jin S H,Kim D H,Jun G H,et al.Tuning the photoluminescence of graphene quantum dots through the charge transfer effect of functional groups[J].ACS Nano,2013,7(2):1239-1245.
[45] Nie H,Li M,Li Q,et al.Carbon dots with continuously tunable full-color emission and their application in ratiometric pH sensing[J].Chemistry of Materials,2014,26(10):3104-3112.
[46] Zhu S,Song Y,Zhao X,et al.The photoluminescence mechanism in carbon dots (graphene quantum dots,carbon nanodots,and polymer dots):current state and future perspective[J].Nano Research,2015,8(2):355-381.
[47] Wen X,Yu P,Toh Y R,et al.Intrinsic and extrinsic fluorescence in carbon nanodots:ultrafast time-resolved fluorescence and carrier dynamics[J].Advanced Optical Materials,2013,1(2):173-178.
基金资助
国家“十三五”重点研发计划—竹基纳米掺杂碳素材料制备关键技术(2017YFD0600804)
PDF
